TITLE

The S1/S2 exciton interaction in 2-pyridone·6-methyl-2-pyridone: Davydov splitting, vibronic coupling, and vibronic quenching

AUTHOR(S)
Heid, Cornelia G.; Ottiger, Philipp; Leist, Roman; Leutwyler, Samuel
PUB. DATE
October 2011
SOURCE
Journal of Chemical Physics;10/21/2011, Vol. 135 Issue 15, p154311
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The excitonic splitting between the S1 and S2 electronic states of the doubly hydrogen-bonded dimer 2-pyridone·6-methyl-2-pyridone (2PY·6M2PY) is studied in a supersonic jet, applying two-color resonant two-photon ionization (2C-R2PI), UV-UV depletion, and dispersed fluorescence spectroscopies. In contrast to the C2h symmetric (2-pyridone)2 homodimer, in which the S1 ← S0 transition is symmetry-forbidden but the S2 ← S0 transition is allowed, the symmetry-breaking by the additional methyl group in 2PY·6M2PY leads to the appearance of both the S1 and S2 origins, which are separated by Δexp = 154 cm-1. When combined with the separation of the S1 ← S0 excitations of 6M2PY and 2PY, which is δ = 102 cm-1, one obtains an S1/S2 exciton coupling matrix element of VAB, el = 57 cm-1 in a Frenkel-Davydov exciton model. The vibronic couplings in the S1/S2 ← S0 spectrum of 2PY·6M2PY are treated by the Fulton-Gouterman single-mode model. We consider independent couplings to the intramolecular 6a′ vibration and to the intermolecular σ′ stretch, and obtain a semi-quantitative fit to the observed spectrum. The dimensionless excitonic couplings are C(6a′) = 0.15 and C(σ′) = 0.05, which places this dimer in the weak-coupling limit. However, the S1/S2 state exciton splittings Δcalc calculated by the configuration interaction singles method (CIS), time-dependent Hartree-Fock (TD-HF), and approximate second-order coupled-cluster method (CC2) are between 1100 and 1450 cm-1, or seven to nine times larger than observed. These huge errors result from the neglect of the coupling to the optically active intra- and intermolecular vibrations of the dimer, which lead to vibronic quenching of the purely electronic excitonic splitting. For 2PY·6M2PY the electronic splitting is quenched by a factor of ∼30 (i.e., the vibronic quenching factor is Γexp = 0.035), which brings the calculated splittings into close agreement with the experimentally observed value. The 2C-R2PI and fluorescence spectra of the tautomeric species 2-hydroxypyridine·6-methyl-2-pyridone (2HP·6M2PY) are also observed and assigned.
ACCESSION #
66715499

 

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